The UK welcomed an influx of graphene experts last week as Manchester University’s 200+ researchers working in the field of 2D materials were joined by hundreds more for Graphene Week 2015. The event, now in its 10th year, has grown from a small European workshop into a five-day conference boasting over 600 attendees and pushing the University Place venue to capacity. The scope of the programme has expanded too; hexagonal boron nitride (hBN), molybdenum disulphide (MoS2) and other related 2D materials have joined graphene on the ‘menu’ of structures being explored by developers. Most recently, the conference has been co-ordinated by the Graphene Flagship – a European drive to capitalize on the many opportunities for 2D materials, which launched in October 2013 and has adopted Graphene Week as its annual conference.

Plenary update: Nobel Prize winner Kostya Novoselov briefed the Graphene Week 2015 audience on major developments in the field of 2D materials.

The European Commission (EC) has given graphene and related 2D materials research a huge boost through its Flagship initiative, but as Thomas Skordas, head of the EC’s FET Flagships Unit, reminded the audience during the conference opening – the funding is not a blank cheque for 10 years. The objective is to deliver economic benefits. So far, Graphene Flagship projects have generated 3x more publications compared with the Horizon 2020 average, but to achieve its long term goal the programme needs to capitalize on this research growth.

Connecting with industry
The challenge of taking graphene and related 2D materials from the lab to the market is a focus issue for TMR+ and its sister journal Translational Materials Research (TMR), and we were delighted to be invited to the Flagship’s latest Graphene Connect workshop, co-located with Graphene Week 2015, to join in the discussion.

New facility: the Graphene Connect networking event focusing on investment opportunities was held at the UK’s National Graphene Institute in Manchester.

The Manchester session was focused on investment opportunities in graphene and related 2D materials, and put the spotlight on start-ups and early-stage companies. Fittingly, the workshop took place at the recently opened National Graphene Institute (NGI) – a facility where academia and industry are co-located to promote translation of 2D materials from the lab to the market.

Presenters from the VC community included Achim Hoffman of IP Group. He picked up on the issue of media hype surrounding graphene, which has distorted expectations. One of the key messages from the session was the need to stay focused on the fundamentals such as the market, the technology and the infrastructure. “You’ve got to go back to basics,” summed up MTI’s Mark Rahn, who also spoke at the event.

Rahn presented a snapshot of companies operating in the graphene sector. Today, materials suppliers are putting resource into stepping up the value chain by offering functionalized products and formulations that are easier for customers to evaluate and integrate. “The real hard work is how you get from a good idea to a viable production process,” said Nigel Salter, Managing Director of 2DTech – a start-up supplying graphene nanoplatelets (GNPs).

Other industrial players at the workshop included BGT Materials, a 2D materials venture with a base in the UK and a sister operation in Taiwan. According to its UK manager – Liam Britnell – BGT has developed an environmentally-friendly way to process graphene-oxide (GO). Applications include barrier films for food packaging, which exploits the material’s very low oxygen transmission characteristics.

Hexagonal highlights: the National Graphene Institute’s carbon-black coloured cladding is patterned with graphene-shaped perforations.

Whether it’s packaging or microelectronics, materials firms need to understand their potential markets and make sure that their products and processes are compatible with their target industries. To accelerate this process, Applied Nanolayers (ANL) – which grew out of Leiden University – decided to break the cord from academia early on and moved south to base itself in the heart of the Netherlands’ chip-making ecosystem. The company provides wafer-grown 2D material such as graphene or hBN for a range of device applications.

Business briefing
The final panel discussion of the day, which featured Graphenea, Haydale and Flexenable, highlighted the many different routes for growing and repositioning businesses in the advanced materials sector – topics that TMR will be exploring in more detail through its journal section ‘Policy, funding and business strategy’.

• Graphenea began as a supplier of 2D materials for the research community, but the firm’s products also appeal to industry and in 2013 it won investment from Repsol – a multinational with activities upstream and downstream in the oil & gas sector. Most recently, Graphenea has been awarded Euro 2.5 million through the Horizon 2020 SME instrument – a phased programme of support to small-to-medium enterprises – which will allow the San Sebastian headquartered company to further scale-up its production capacity. The firm has a satellite office based in Boston, US, to strengthen its links with MIT and Harvard.
• Haydale has raised capital by floating on the London Stock Exchange, and recently acquired EPL Composites, which gives the firm an immediate route into this applications area. Haydale has built a strong case for the benefits of graphene functionalization through independent testing of its materials by the UK’s national measurement institute – NPL.
• FlexEnable was spun out of Plastic Logic to give the business more freedom to apply its expertise in printing transistors on plastic beyond the display sector. Its activities include consulting services to materials companies.

Meanwhile, back at Graphene Week
There was plenty of industry input at the main conference too with updates from Bosch, IBM and Alcatel Lucent, to name just a few of the big names eyeing up opportunities for 2D materials. TMR+ spoke with IBM’s Shu-Jen Han last year, and the message remains the same in 2015 – RF devices rather than digital logic are a stronger proposition for graphene. Telecomms could be a promising area for the material thanks to graphene’s consistent performance across a wide temperature range, and useful optical properties.

Smart space: The National Graphene Institute features a ‘high-rise wildflower meadow’ designed to improve roof function by providing a green space for people and pollinators such as bees, butterflies and hoverflies. For a video tour of the building, including the lab space, check out the YouTube clip from TMR+’s sister site physicsworld.com.

Alcatel Lucent has been working with partner AMO Aachen to investigate the potential of 2D materials in enabling highly-integrated photonic subsystems. The team has come up with a photodetector featuring CVD-grown graphene on a Si waveguide, which operates in the c-band (wavelength = 1550 nm) to support data rates up to 50 GBit/s.

The next Graphene Connect workshop is scheduled for early 2016 and will explore the topic of biosensors and implants. Graphene Week 2016 will take place in Poland next June.

Related articles from TMR
Graphene Connect underscores the importance of engaging SMEs in materials commercialization – Transl. Mater. Res. 2 010203 (2015)

Related stories from TMR+
Fullerex talks graphene pricing; identifies growth areas and supply targets

IDTechEx’s multi-track conference and exhibition explores the interconnected landscape of printed electronics, wearable technology, energy harvesting, the internet of things (IoT), graphene and 2D materials, 3D printing, and electric vehicles. Collaboration is key to succeeding in materials translation, and for me this was one of the big messages of the 2015 show, which brings together formulation specialists, systems developers, fabrication experts, measurement providers, and customer groups, all under the same roof for two days (or more if you sign-up to masterclasses).

Keynote welcome: Raghu Das, CEO of IDTechEx, briefs the audience on market projections for the printed electronics sector.

Dialogue between technology providers and end-users helps to resolve uncertainty in emerging fields such as printed and flexible electronics where – i) customers can be unsure about what’s possible and ii) suppliers need guidance on market requirements.

Bringing new technology to market
On day one, speakers from Qualcomm and Flextronics outlined how their firms bring new technology to the market. In Qualcomm’s case, its approach is built on four pillars – i) system R&D leadership, ii) design for manufacturability, iii) supply chain management and iv) customer support and engineering. It’s important not to overlook the final step. “The value proposition is only realized if you can propagate this to the customer,” Stein Lundby (R&D manager at Qualcomm) reiterated to audience.

Qualcomm, which Lundby describes as a ‘surface electronics’ company, is exploring opportunities for a hybrid product combining traditional crystalline based electronics with printed electronic components. Developed with Enfucell – a provider of printed power sources – the device features a 3-axis gyroscope and 3-axis accelerometer together with integrated battery and system electronics packaged in a band-aid style form factor. Users can stick the sensor on items such as golf clubs to determine how new products might improve their game, but this is just one possible scenario.

To navigate markets such as wearables, Flextronics – which focuses on production equipment and know-how – has opened design centres to help customers with product development and new use-cases such as electronic displays for athletic clothing. In his presentation, Keith Churches (head of innovation services at Flextronics) showed how the company brings new ideas to the market by configuring product-specific development networks that link the firm’s expertise with partners such as OEMs, universities and research institutes.

Nanomaterials
Directa Plus – which was founded in 2005 and opened its graphene factory in 2014 – used the graphene and 2D materials conference track to talk through its collaboration with Vittoria Industries and highlight early market opportunities for graphene. Dubbed the wonder material, graphene – an ultra-thin layer of carbon – has been shown to have record-breaking electrical, thermal and mechanical properties, but breakthrough results in the lab don’t guarantee commercial success. “You have to be brave to be in the graphene market,” Giulio Cesareo (CEO of Directa Plus) commented.

Full house: interest in graphene and related 2D materials remains strong.

Vittoria uses Directa Plus’ graphene nanoplatelets to formulate bicycle tyres and wheels with enhanced properties such as heat dissipation and lateral stiffness. There are 165 wheel makers in the world, Rudi Campagne (founder of Vittoria Industries) told the audience, and the use of nanomaterials such as graphene is an effective way for Vittoria to differentiate itself from the competition.

Early uses of graphene provide a platform for growth in other sectors by establishing a materials supply chain. Beyond tyres and wheels, Directa Plus is looking at opportunities for graphene in cleaning up contaminated soil and water. In his talk, Cesareo explained that linked graphene platelets have the potential to remove hydrocarbon pollution from lakes, according to test results. Literature from the firm claims that 1 gram of its Graphene Plus sorbent can adsorb up to 80-90 grams of oil – for more details, visit the GEnIuS project website, a programme co-founded by European Union within the Eco-Innovation initiative.

Exhibition: new products launched at the show included Ceradrop’s ‘F-Serie’ multi-material printer.

The discussion then moved on to opportunities for 2D materials in the electronics industry. If graphene does make an impact in this sector it is likely to be driven by novel applications, based on the views of the speakers in the opening session. “Graphene will not replace silicon in standard devices,” commented Guenther Ruhl (lead principal in new materials at Infineon Technologies) during his talk.

Touch screens are also looking unlikely as a big opportunity for graphene. “Graphene transparent conductive films are among the worst performers in a crowded market,” explained Khasha Ghaffarzadeh (head of consulting at IDTechEx). Like Ruhl, he feels that 2D materials could have more impact in new product categories. “The beauty of graphene is that there are many target industries and applications,” Ghaffarzadeh added.

OPV and R2R technology
Analyst events such as the IDTechEx show give attendees a view on tomorrow’s technology today. Two further highlights for me from the keynote presentations were Heliatek’s building integrated photovoltaics (BIPV) and Asahi Kasei’s e-beam fabricated seamless roller for printing transistors.

Show venue: Estrel, Berlin

In the afternoon on day one, Martin Pfeiffer (chief technology officer at Heliatek) outlined what he feels is a sweet spot for OPV – active facades. To compete with silicon, OPV has to bring something different, which it can when applications demand flexible and lightweight solutions. He added that the energy payback for an OPV cell can be as little as 3 months, as determined by the EU project dubbed X10D. Pfeiffer revealed that large-scale trials of the firm’s material were now underway in China and Germany on concrete (in Shanghai), PVC membrane (in Berlin) and glass (in Dresden) structures, with another pilot project due to start soon in Singapore on a glass and steel construction.

There were more glimpses of the future on day two when Masayuki Abe of Japanese giant Asahi Kasei – which operates in chemicals, electronics and healthcare sectors – presented his team’s work on seamless roller mold (SRM) technology for roll-to-roll (R2R) printing of sub-micron feature sizes. To make the mold, they rotated a super-smooth (2 nm roughness) roller under an e-beam writer. Moving the roller laterally (as well as rotating it) allows the team to create complex mold patterns. To test the process, Abe’s group used one of its roller molds to print a 200 ppi, 125 micron pitch TFT array. Abe was clearly proud of his team’s results and sees a bright future for the technique. “SRM will bring about the realization of high-resolution printing,” he told the audience.

Dates for your diary
The IDTechEx conference and exhibition takes place twice annually – once in Europe and once in the US (18-19 Nov 2015). The event returns to Berlin on the 27th and 28th of April 2016.

Related stories on TMR+

MC10 declares that the future of electronics is flexible
Roll-to-roll production could ramp up market opportunities for graphene
Show report: Metal additive manufacturing 2014 (Sheffield, UK)
Fullerex talks graphene pricing; identifies growth areas and supply targets

Related articles from the journal Translational Materials Research

Industrial-scale inkjet printed electronics manufacturing—production up-scaling from concept tools to a roll-to-roll pilot line – Robert Abbel et al 2014 Transl. Mater. Res. 1 015002
Singlet harvesting copper-based emitters: a modular approach towards next-generation OLED technology – Daniel M Zink et al 2014 Transl. Mater. Res. 1 015003
Analysis of the electrical and optical properties of PEDOT:PSS/PVA blends for low-cost and high-performance organic electronic and optoelectronic devices – Olivia Carr et al 2015 Transl. Mater. Res. 2 015002

Related stories on the web

New Graphene Factory opens in Italy (nanotechweb.org)